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DTSTAMP:20201221T213120Z
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DTSTART;TZID=Canada/Pacific:20201218T130000
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DESCRIPTION:Abstract: Hydrophobic surfaces that are robust can have widespr
 ead applications in various industries including energy\, hydropower\, and
  transportation. Existing durable materials such as metals and ceramics ar
 e generally hydrophilic and require polymeric modifiers to render them hyd
 rophobic\, but these modifiers deteriorate in harsh environments. Therefor
 e\, robust hydrophobic surfaces have been difficult to realize and their w
 idespread applicability has been limited. In this talk\, the class of cera
 mics comprising the lanthanide series rare-earth oxides (REOs) will be dis
 cussed for their potential in enhancing the longevity of sustainable energ
 y systems by repelling water. The unique electronic structure of the rare-
 earth metal atom inhibits hydrogen bonding with interfacial water molecule
 s resulting in a hydrophobic hydration structure where the surface oxygen 
 atoms are the only hydrogen bonding sites. Despite being inherently hydrop
 hobic\, the presence of excess surface oxygen on REOs can lead to increase
 d hydrogen bonding and thereby reduce their hydrophobicity. Using X-ray Ph
 otoelectron Spectroscopy (XPS) and wetting measurements\, surface stoichio
 metry and surface relaxations have been shown to impact wetting properties
  of REOs. Specifically\, freshly sputtered ceria is shown to be hydrophili
 c due to excess surface oxygen (shown to have an O/Ce ratio of ~3)\, which
  when relaxed in a clean\, ultra-high vacuum environment isolated from air
 borne hydrocarbons reaches close to stoichiometric O/Ce ratio (~2.2) and b
 ecomes hydrophobic. We also demonstrate that thin-film coatings (~300 nm) 
 of hydrophobic REOs show sustained dropwise condensation behaviour for ove
 r 100 hours at accelerated saturated steam conditions without compromising
  structural integrity or hydrophobicity\, and produce a tenfold enhancemen
 t in the heat transfer co-efficient (103 ± 5 kW/m2K) compared to conventi
 onal filmwise condensation (usually &lt;10 kW/m2K). We will discuss applicati
 ons of such hydrophobic surfaces in electronic devices and discuss embodim
 ents with self-healing lubricant-infused surfaces that can provide corrosi
 on protection in sustainable energy systems.\n\nSpeaker(s): Dr. Sami Khan\
 , \n\nBurnaby\, British Columbia\, Canada\, V5A 1S6\, Virtual: https://eve
 nts.vtools.ieee.org/m/250828
LOCATION:Burnaby\, British Columbia\, Canada\, V5A 1S6\, Virtual: https://e
 vents.vtools.ieee.org/m/250828
ORGANIZER:mmadachi@sfu.ca
SEQUENCE:1
SUMMARY:IEEE Electron Device Invited Talk by Dr. Sami Khan\, Simon Fraser U
 niversity - Robust Hydrophobic Surfaces for Enhancing Longevity of Sustain
 able Energy Systems
URL;VALUE=URI:https://events.vtools.ieee.org/m/250828
X-ALT-DESC:Description: &lt;br /&gt;&lt;p&gt;&lt;strong&gt;Abstract:&lt;/strong&gt; Hydrophobic sur
 faces that are robust can have widespread applications in various industri
 es including energy\, hydropower\, and transportation. Existing durable ma
 terials such as metals and ceramics are generally hydrophilic and require 
 polymeric modifiers to render them hydrophobic\, but these modifiers deter
 iorate in harsh environments. Therefore\, robust hydrophobic surfaces have
  been difficult to realize and their widespread applicability has been lim
 ited. In this talk\, the class of ceramics comprising the lanthanide serie
 s rare-earth oxides (REOs) will be discussed for their potential in enhanc
 ing the longevity of sustainable energy systems by repelling water. The un
 ique electronic structure of the rare-earth metal atom inhibits hydrogen b
 onding with interfacial water molecules resulting in a hydrophobic hydrati
 on structure where the surface oxygen atoms are the only hydrogen bonding 
 sites. Despite being inherently hydrophobic\, the presence of excess surfa
 ce oxygen on REOs can lead to increased hydrogen bonding and thereby reduc
 e their hydrophobicity. Using X-ray Photoelectron Spectroscopy (XPS) and w
 etting measurements\, surface stoichiometry and surface relaxations have b
 een shown to impact wetting properties of REOs. Specifically\, freshly spu
 ttered ceria is shown to be hydrophilic due to excess surface oxygen (show
 n to have an O/Ce ratio of ~3)\, which when relaxed in a clean\, ultra-hig
 h vacuum environment isolated from airborne hydrocarbons reaches close to 
 stoichiometric O/Ce ratio (~2.2) and becomes hydrophobic. We also demonstr
 ate that thin-film coatings (~300 nm) of hydrophobic REOs show sustained d
 ropwise condensation behaviour for over 100 hours at accelerated saturated
  steam conditions without compromising structural integrity or hydrophobic
 ity\, and produce a tenfold enhancement in the heat transfer co-efficient 
 (103 &amp;plusmn\; 5 kW/m&lt;sup&gt;2&lt;/sup&gt;K) compared to conventional filmwise cond
 ensation (usually &amp;lt\;10 kW/m&lt;sup&gt;2&lt;/sup&gt;K). We will discuss applications
  of such hydrophobic surfaces in electronic devices and discuss embodiment
 s with self-healing lubricant-infused surfaces that can provide corrosion 
 protection in sustainable energy systems.&lt;/p&gt;\n&lt;p&gt;&amp;nbsp\;&lt;/p&gt;
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