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DTSTAMP:20250919T173239Z
UID:300DECDD-8894-4E17-B093-041257EBD83E
DTSTART;TZID=America/New_York:20250918T110000
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DESCRIPTION:Abstract: In this talk\, we will discuss two recent observation
 s from our group that have challenged widespread assumptions held (by us i
 ncluded!) about the optical response of commonly used optical materials: t
 hat material polarization can safely be considered to respond locally to t
 he electric field and that the second-order nonlinear response of amorphou
 s films should vanish due to centrosymmetry. In the first part of the talk
 \, we will describe our proposal for a new type of optical antenna dubbed 
 a “photonic gap antenna”\, and our realization of its extreme version 
 using an epsilon-near-zero (ENZ) material. Such antennas can provide elect
 ric field enhancements of &gt;100 and large Purcell factors without requiring
  stringent nanofabrication. To our surprise\, when measuring third harmoni
 c generation as a proxy for field enhancement\, sharp peaks emerge in the 
 response that are completely absent in our full wave electromagnetic calcu
 lations. We find that the appearance of these peaks can only be explained 
 when including nonlocality in the dielectric response of the ENZ material.
  Nonlocal simulations show that the volume averaged field enhancement can 
 be 4–6 greater than that predicted by the local model\, which becomes an
  important consideration when designing optical devices. In the second par
 t of the talk\, we will describe our recent discovery that amorphous therm
 ally evaporated organic thin films of small molecules can have second-orde
 r optical nonlinearities on par with those of state-of-the-art nonlinear m
 aterials (c(2)31\, c(2)33 &gt;50 pm/V)\, with the important advantage that th
 ey can be deposited on arbitrary photonic platforms. We will show that by 
 harnessing the interplay between dipole-dipole interactions and surface en
 ergy minimization\, it is possible to spontaneously break centrosymmetry d
 uring thermal evaporation\, without the need for special alignment procedu
 res. In addition to its applications in photonics\, this observation has a
 llowed us to better understand molecular alignment beyond the mean molecul
 ar orientation angle.\n\n.\n\nCo-sponsored by: Prof. Nicolas Quesada\n\nSp
 eaker(s): Stéphane Kéna-Cohen\n\nJ. Armand Bombardier J-1035\, Polytechn
 ique Montréal\, Montréal\, Quebec\, Canada\, H3T 1J4
LOCATION:J. Armand Bombardier J-1035\, Polytechnique Montréal\, Montréal\
 , Quebec\, Canada\, H3T 1J4
ORGANIZER:nicolas.quesada@polymtl.ca
SEQUENCE:118
SUMMARY:Recent surprises in nonlocal and nonlinear photonics
URL;VALUE=URI:https://events.vtools.ieee.org/m/499775
X-ALT-DESC:Description: &lt;br /&gt;&lt;div&gt;&lt;img src=&quot;https://events.vtools.ieee.org
 /vtools_ui/media/display/2d62542a-7acc-458f-84f6-5fe2d1ef15e0&quot; width=&quot;917&quot;
  height=&quot;509&quot;&gt;&lt;/div&gt;\n&lt;div&gt;&amp;nbsp\;&lt;/div&gt;\n&lt;div&gt;&lt;span style=&quot;font-family: &#39;
 times new roman&#39;\, times\, serif\;&quot;&gt;&lt;strong&gt;Abstract: &lt;/strong&gt;&lt;span style
 =&quot;font-size: 12pt\;&quot;&gt;&lt;span lang=&quot;EN-CA&quot; style=&quot;font-family: &#39;Times New Rom
 an&#39;\, serif\;&quot;&gt;In this talk\, we will discuss two recent observations from
  our group that have challenged widespread assumptions held (by us include
 d!) about the optical response of commonly used optical materials: that ma
 terial polarization can safely be considered to respond locally to the ele
 ctric field and that the second-order nonlinear response of amorphous film
 s should vanish due to centrosymmetry. In the first part of the talk\, we 
 will describe our proposal for a new type of optical antenna dubbed a &amp;ldq
 uo\;photonic gap antenna&amp;rdquo\;\, and our realization of its extreme vers
 ion using an epsilon-near-zero (ENZ) material. Such antennas can provide e
 lectric field enhancements of &amp;gt\;100 and large Purcell factors without r
 equiring stringent nanofabrication. To our surprise\, when measuring third
  harmonic generation as a proxy for field enhancement\, sharp peaks emerge
  in the response that are completely absent in our full wave electromagnet
 ic calculations. We find that the appearance of these peaks can only be ex
 plained when including nonlocality in the dielectric response of the ENZ m
 aterial. Nonlocal simulations show that the volume averaged field enhancem
 ent can be 4&amp;ndash\;6 greater than that predicted by the local model\, whi
 ch becomes an important consideration when designing optical devices. In t
 he second part of the talk\, we will describe our recent discovery that am
 orphous thermally evaporated organic thin films of small molecules can hav
 e second-order optical nonlinearities on par with those of state-of-the-ar
 t nonlinear materials (&lt;/span&gt;&lt;span lang=&quot;EN-CA&quot; style=&quot;font-family: Symbo
 l\;&quot;&gt;c&lt;sup&gt;(2)&lt;/sup&gt;&lt;/span&gt;&lt;sub&gt;&lt;span lang=&quot;EN-CA&quot; style=&quot;font-family: &#39;Ti
 mes New Roman&#39;\, serif\;&quot;&gt;31&lt;/span&gt;&lt;/sub&gt;&lt;span lang=&quot;EN-CA&quot; style=&quot;font-fa
 mily: &#39;Times New Roman&#39;\, serif\;&quot;&gt;\, &lt;/span&gt;&lt;span lang=&quot;EN-CA&quot; style=&quot;fon
 t-family: Symbol\;&quot;&gt;c&lt;sup&gt;(2)&lt;/sup&gt;&lt;/span&gt;&lt;sub&gt;&lt;span lang=&quot;EN-CA&quot; style=&quot;f
 ont-family: &#39;Times New Roman&#39;\, serif\;&quot;&gt;33&lt;/span&gt;&lt;/sub&gt;&lt;span lang=&quot;EN-CA&quot;
  style=&quot;font-family: &#39;Times New Roman&#39;\, serif\;&quot;&gt; &amp;gt\;50 pm/V)\, with th
 e important advantage that they can be deposited on arbitrary photonic pla
 tforms. We will show that by harnessing the interplay between dipole-dipol
 e interactions and surface energy minimization\, it is possible to spontan
 eously break centrosymmetry during thermal evaporation\, without the need 
 for special alignment procedures. In addition to its applications in photo
 nics\, this observation has allowed us to better understand molecular alig
 nment beyond the mean molecular orientation angle&lt;/span&gt;.&lt;/span&gt;&lt;/span&gt;\n&lt;
 p aria-hidden=&quot;true&quot;&gt;&lt;span style=&quot;font-family: &#39;times new roman&#39;\, times\,
  serif\;&quot;&gt;&amp;nbsp\;&lt;/span&gt;&lt;/p&gt;\n.&lt;/div&gt;
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