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DESCRIPTION:Green hydrogen produced through the thermochemical reforming of
  agricultural residues presents a sustainable solution for mitigating glob
 al warming. Corn stover\, a renewable and carbon-rich agricultural residue
 \, is an efficient feedstock for sustainable green hydrogen production via
  thermochemical processes. In this work\, A 2kg lab scale thermo-catalytic
  reforming unit consisting of an intermediate pyrolysis auger reactor (400
  - 500 °C) and a reformer (500 - 700 °C) was used to focus on hydrogen-r
 ich TCR gas production. We also characterized the resulting pyrolysis prod
 ucts\, including bio-oil and char. The optimum reactor and reformer temper
 atures for TCR gas production were identified as 500°C and 675°C\, respe
 ctively. Under these conditions\, organic liquid production was 2.44%\, ch
 ar production was 25.37%\, and TCR gas production was 58.55%\, with 22.96%
  being H2. The syngas produced\, with an HHV of 7.91 MJ/Nm3\, serves as a 
 precursor for advanced processes like Fischer-Tropsch and Haber-Bosch\, en
 abling the production of synthetic fuels and chemicals. The bio-oil produc
 ed under these conditions demonstrated favourable characteristics\, includ
 ing an HHV of 34.85 MJ/kg\, an O/C ratio of 0.12\, and an H/C ratio of 0.0
 8. These values indicate improved bio-oil quality compared to lower reform
 ing temperatures (400/500°C)\, which yielded an HHV of 28.76 MJ/kg\, an O
 /C ratio of 0.38\, and an H/C ratio of 0.12. At 25°C\, the density of the
  bio-oil was 1080 kg/m3\, with a dynamic viscosity of 45.6 mPa·s and a ki
 nematic viscosity of 42.4 mm2/s. The char produced at 500/675°C had an HH
 V of 11.71 MJ/kg\, compared to 15.89 MJ/kg at 400/500°C\, and offers pote
 ntial as a secondary fuel in combined heat and power (CHP) systems. SEM an
 alysis revealed high surface porosity in the biochar\, confirming its suit
 ability for surface water phosphorus absorption. Our findings suggest that
  intermediate pyrolysis coupled with catalytic reforming is a promising pa
 thway for green hydrogen generation and valorization of pyrolysis byproduc
 ts\, with potential applications in renewable energy and sustainable agric
 ulture.\n\nCo-sponsored by: Resilience and Clean Energy Systems (RCES)\n\n
 Speaker(s): Ebenezer  Adewola\n\nVirtual: https://events.vtools.ieee.org/m
 /502174
LOCATION:Virtual: https://events.vtools.ieee.org/m/502174
ORGANIZER:xiaotin5@ualberta.ca
SEQUENCE:4
SUMMARY:Hydrogen generation via dry reforming of corn stover pellets using 
 corn stover biochar as catalyst
URL;VALUE=URI:https://events.vtools.ieee.org/m/502174
X-ALT-DESC:Description: &lt;br /&gt;&lt;p&gt;&lt;em&gt;Green hydrogen produced through the th
 ermochemical reforming of agricultural residues presents a sustainable sol
 ution for mitigating global warming. Corn stover\, a renewable and carbon-
 rich agricultural residue\, is an efficient feedstock for sustainable gree
 n hydrogen production via thermochemical processes. In this work\, A 2kg l
 ab scale thermo-catalytic reforming unit consisting of an intermediate pyr
 olysis auger reactor (400 - 500 &amp;deg\;C) and a reformer (500 - 700 &amp;deg\;C
 ) was used to focus on hydrogen-rich TCR gas production. We also character
 ized the resulting pyrolysis products\, including bio-oil and char. The op
 timum reactor and reformer temperatures for TCR gas production were identi
 fied as 500&amp;deg\;C and 675&amp;deg\;C\, respectively. Under these conditions\,
  organic liquid production was 2.44%\, char production was 25.37%\, and TC
 R gas production was 58.55%\, with 22.96% being H2. The syngas produced\, 
 with an HHV of 7.91 MJ/Nm3\, serves as a precursor for advanced processes 
 like Fischer-Tropsch and Haber-Bosch\, enabling the production of syntheti
 c fuels and chemicals. The bio-oil produced under these conditions demonst
 rated favourable characteristics\, including an HHV of 34.85 MJ/kg\, an O/
 C ratio of 0.12\, and an H/C ratio of 0.08. These values indicate improved
  bio-oil quality compared to lower reforming temperatures (400/500&amp;deg\;C)
 \, which yielded an HHV of 28.76 MJ/kg\, an O/C ratio of 0.38\, and an H/C
  ratio of 0.12. At 25&amp;deg\;C\, the density of the bio-oil was 1080 kg/m3\,
  with a dynamic viscosity of 45.6 mPa&amp;middot\;s and a kinematic viscosity 
 of 42.4 mm2/s. The char produced at 500/675&amp;deg\;C had an HHV of 11.71 MJ/
 kg\, compared to 15.89 MJ/kg at 400/500&amp;deg\;C\, and offers potential as a
  secondary fuel in combined heat and power (CHP) systems. SEM analysis rev
 ealed high surface porosity in the biochar\, confirming its suitability fo
 r surface water phosphorus absorption. Our findings suggest that intermedi
 ate pyrolysis coupled with catalytic reforming is a promising pathway for 
 green hydrogen generation and valorization of pyrolysis byproducts\, with 
 potential applications in renewable energy and sustainable agriculture.&lt;/e
 m&gt;&lt;/p&gt;
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